Crystal structures of the isotypic complexes bis(morpholine)gold(I) chloride and bis(morpholine)gold(I) bromide

Döring, Cindy; Jones, Peter G.

doi:10.1107/S2056989023009702

Article / Chapter Thu Nov 16 2023 CC BY 4.0

Published

Crystal structures of the isotypic complexes bis(morpholine)gold(I) chloride and bis(morpholine)gold(I) bromide

The compounds bis(morpholine-κN)gold(I) chloride, [Au(C₄H₉NO)₂]Cl, 1, and bis(morpholine-κN)gold(I) bromide, [Au(C₄H₉NO)₂]Br, 2, crystallize isotypically in space group C2/c with Z = 4. The gold atoms, which are axially positioned at the morpholine rings, lie on inversion centres (so that the N—Au—N coordination is exactly linear) and the halide anions on twofold axes. The residues are connected by a classical hydrogen bond N—H⋯halide and by a short gold⋯halide contact to form a layer structure parallel to the bc plane. The morpholine oxygen atom is not involved in classical hydrogen bonding.