Crystal structure of 2-(benzo[d]thia-zol-2-yl)-3,3-bis-(ethyl-sulfan-yl)acrylo-nitrile

Azzam, Rasha A; Elgemeie, Galal H; Elsayed, Rasha E; Gad, Nagwa M; Jones, Peter G

doi:10.1107/S2056989022002572

Article / Chapter Mon Mar 7 2022 CC BY 4.0

Published

Crystal structure of 2-(benzo[d]thia-zol-2-yl)-3,3-bis-(ethyl-sulfan-yl)acrylo-nitrile

Azzam, Rasha A ; Elgemeie, Galal H; Elsayed, Rasha E; Gad, Nagwa M; Jones, Peter G

In the title compound, C₁₄H₁₄N₂S₃, the double-bond system of the acrylo-nitrile moiety is significantly non-planar, with absolute cis torsion angles of 13.9 (2) and 15.1 (2)°. The ring system and the double bond system subtend an inter-planar angle of 11.16 (4)°. The wide angle C-C(CN)=C of 129.40 (12)° may be associated with a balance between planarity and avoidance of a very short S⋯S contact.