Crystal structure of N'-[2-(benzo[d]thia-zol-2-yl)acet-yl]benzohydrazide, an achiral compound crystallizing in space group P1 with Z = 1.

Azzam, Rasha A.; Elgemeie, Galal H.; Seif, Mona M.; Jones, Peter G.

doi:10.1107/S2056989021007672

Article / Chapter Tue Jul 27 2021 CC BY 4.0

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Crystal structure of N'-[2-(benzo[d]thia-zol-2-yl)acet-yl]benzohydrazide, an achiral compound crystallizing in space group P1 with Z = 1.

Azzam, Rasha A.; Elgemeie, Galal H.; Seif, Mona M.; Jones, Peter G.

In the molecule of the title compound, C₁₆H₁₃N₃O₂S, one hydrazinic nitrogen atom is essentially planar, but the other is slightly pyramidalized. The torsion angle about the hydrazinic bond is 66.44 (15)°. Both hydrazinic hydrogen atoms lie anti-periplanar to the oxygen of the adjacent carbonyl group. The mol-ecular packing is a layer structure determined by two classical hydrogen bonds, N-H⋯O=C and N-H⋯N_thia-zole. The space group is P1 with Z = 1, which is unusual for an achiral organic compound.