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Crystal structure of akuammicine, an indole alkaloid from Catharanthus roseus

GND
1145309194
Affiliation/Institute
Institut für Pflanzenbiologie, Technische Universität Braunschweig
Yahyazadeh, Mahdi;
GND
121453766
Affiliation/Institute
Institut für Lebensmittelchemie, Technische Universität Braunschweig
Jerz, Gerold;
GND
121416429
Affiliation/Institute
Institut für Pflanzenbiologie, Technische Universität Braunschweig
Selmar, Dirk;
GND
1144500281
Affiliation/Institute
Institut für Lebensmittelchemie, Technische Universität Braunschweig
Winterhalter, Peter;
GND
1132099900
Affiliation/Institute
Institut für Anorganische und Analytische Chemie, Technische Universität Braunschweig
Jones, Peter G.

The title compound, C20H22N2O2, an alkaloid isolated from the Madagascar periwinkle, crystallizes in P1 with two independent but closely similar mol­ecules in the unit cell. The mol­ecules are linked into pairs by two N—H⋯O=C hydrogen bonds. The absolute configuration was confirmed by anomalous dispersion effects as S at the 3 and 15 positions, and R at the 7 position.

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